Sunkern made its debut appearance in In motion Pictures. Ash, Brock, Misty, while Todd Snap found it frozen all the way through a field. Ash eventually changed it using his Sun Stone by way of The Bug Stops Here, and the situation summoned more Sunflora so that Sophia and Marcello could take a photos for their golden anniversary.
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By Volume 8, Gold encounters a herd of Sunkern escaping from a Skarmory. He captures one of typically the Sunkern to help defeat the Skarmory with Exbo's Ember attack using it is really jumping Ability. Although not far of a battler and used sparingly, in Volume 14, she evolves straight into Sunflora and uses its Sunny Big day to power up the Typhlosion's start attacks, helping it combat the Hidden Man.
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Chikorita later was used in Once All through a Blue Moon to try choosing the GS Ball back. However, Chikorita only wanted to be affectionate, so when Quagsire got near Ash, Chikorita got angry and tries to allow them to hit it with her leaf but unfortunately she accidently hits Ash instead.